If you do not have SMTP installed in your corporate, you can use smtp.gmail.com with port 587.
As for user to log on to the vcenter, if you are using a domain user, you need to use this format instead - "username@domainname" rather than "domain name\username".
As for user to log on to the vcenter, if you are using a domain user, you need to use this format instead - "username@domainname" rather than "domain name\username".
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